A first time faculty member will not be given a position as department chair anywhere.
Or, if there exists an exception, it is a place where you very much don't want to work. Trust me on this.
Yeah, I was just going to write that my former institution had a number of untenured chairs. You do not want to be an untenured chair. As chair, you have to make decisions that will upset people, and if those same people will one day make up your tenure committee, that's a recipe for disaster.
Moreover, a good rule of thumb, at least in my field and in my experience, is that when a dept. is conducting a search for an outside chair, it means that the dept. is dysfunctional and the Dean has decided to bring someone in from the outside to straighten them out and make them play nice.
In short, I don't think it sounds great, but in this job market, I also wouldn't pass up any openings.